 |
Journal articles
Iridium-catalysed asymmetric allylic alkylation of benzofuran γ-lactones followed by heteroaromatic Cope rearrangement: study of an unusual reaction sequence
Abstract : The iridium-catalysed asymmetric allylic alkylation of γ-lactones produces an all-carbon quaternary stereocentre substituted by an allyl and a benzofuran. The resulting 1,5-hexadienes were found to be excellent substrates for an unusual heteroaromatic Cope rearrangement. We describe here the first insight into the synthetic outcome of this intriguing reaction sequence.
https://hal.univ-reims.fr/hal-02429296
Contributor : Emmanuel Riguet <>
Submitted on : Monday, January 6, 2020 - 3:25:19 PM
Last modification on : Monday, April 19, 2021 - 8:51:05 AM
Contributor : Emmanuel Riguet <>
Submitted on : Monday, January 6, 2020 - 3:25:19 PM
Last modification on : Monday, April 19, 2021 - 8:51:05 AM