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Photoorganocatalysed and visible light photoredox catalysed trifluoromethylation of olefins and (hetero)aromatics in batch and continuous flow

Abstract : Trifluoromethylation of olefins and (hetero)aromatics with sodium triflinate as CF3 source and readily accessible benzophenone derivatives as photosensitisers has been developed in batch and flow. The use of an iridium-based photocatalyst enables the trifluoromethylation to proceed under visible light irradiation.
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https://hal.univ-reims.fr/hal-01840436
Contributor : Norbert Hoffmann <>
Submitted on : Monday, July 16, 2018 - 2:09:45 PM
Last modification on : Thursday, March 5, 2020 - 6:56:52 PM

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Quentin Lefebvre, Norbert Hoffmann, Magnus Rueping. Photoorganocatalysed and visible light photoredox catalysed trifluoromethylation of olefins and (hetero)aromatics in batch and continuous flow. Chemical Communications, Royal Society of Chemistry, 2016, 52 (12), pp.2493 - 2496. ⟨10.1039/C5CC09881E⟩. ⟨hal-01840436⟩

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