Photoorganocatalysed and visible light photoredox catalysed trifluoromethylation of olefins and (hetero)aromatics in batch and continuous flow

Quentin Lefebvre 1 Norbert Hoffmann 2 Magnus Rueping 1
1 RWTH - Rheinisch-Westfälische Technische Hochschule Aachen
2 ICMR - Institut de Chimie Moléculaire de Reims - UMR 7312
Abstract : Trifluoromethylation of olefins and (hetero)aromatics with sodium triflinate as CF3 source and readily accessible benzophenone derivatives as photosensitisers has been developed in batch and flow. The use of an iridium-based photocatalyst enables the trifluoromethylation to proceed under visible light irradiation.
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Journal articles
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https://hal.univ-reims.fr/hal-01840436
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Submitted on : Monday, July 16, 2018 - 2:09:45 PM
Last modification on : Thursday, December 12, 2019 - 12:00:27 PM

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Quentin Lefebvre, Norbert Hoffmann, Magnus Rueping. Photoorganocatalysed and visible light photoredox catalysed trifluoromethylation of olefins and (hetero)aromatics in batch and continuous flow. Chemical Communications, Royal Society of Chemistry, 2016, 52 (12), pp.2493 - 2496. ⟨10.1039/C5CC09881E⟩. ⟨hal-01840436⟩

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