Photoorganocatalysed and visible light photoredox catalysed trifluoromethylation of olefins and (hetero)aromatics in batch and continuous flow - Université de Reims Champagne-Ardenne Accéder directement au contenu
Article Dans Une Revue Chemical Communications Année : 2016

Photoorganocatalysed and visible light photoredox catalysed trifluoromethylation of olefins and (hetero)aromatics in batch and continuous flow

Résumé

Trifluoromethylation of olefins and (hetero)aromatics with sodium triflinate as CF3 source and readily accessible benzophenone derivatives as photosensitisers has been developed in batch and flow. The use of an iridium-based photocatalyst enables the trifluoromethylation to proceed under visible light irradiation.

Dates et versions

hal-01840436 , version 1 (16-07-2018)

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Citer

Quentin Lefebvre, Norbert Hoffmann, Magnus Rueping. Photoorganocatalysed and visible light photoredox catalysed trifluoromethylation of olefins and (hetero)aromatics in batch and continuous flow. Chemical Communications, 2016, 52 (12), pp.2493 - 2496. ⟨10.1039/C5CC09881E⟩. ⟨hal-01840436⟩
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