Photoorganocatalysed and visible light photoredox catalysed trifluoromethylation of olefins and (hetero)aromatics in batch and continuous flow - Université de Reims Champagne-Ardenne Access content directly
Journal Articles Chemical Communications Year : 2016

Photoorganocatalysed and visible light photoredox catalysed trifluoromethylation of olefins and (hetero)aromatics in batch and continuous flow

Abstract

Trifluoromethylation of olefins and (hetero)aromatics with sodium triflinate as CF3 source and readily accessible benzophenone derivatives as photosensitisers has been developed in batch and flow. The use of an iridium-based photocatalyst enables the trifluoromethylation to proceed under visible light irradiation.

Dates and versions

hal-01840436 , version 1 (16-07-2018)

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Quentin Lefebvre, Norbert Hoffmann, Magnus Rueping. Photoorganocatalysed and visible light photoredox catalysed trifluoromethylation of olefins and (hetero)aromatics in batch and continuous flow. Chemical Communications, 2016, 52 (12), pp.2493 - 2496. ⟨10.1039/C5CC09881E⟩. ⟨hal-01840436⟩
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