New oleanane-type saponins: Leptocarposide B-D, from Ludwigia leptocarpa (Onagraceae) - Université de Reims Champagne-Ardenne Accéder directement au contenu
Article Dans Une Revue Phytochemistry Letters Année : 2015

New oleanane-type saponins: Leptocarposide B-D, from Ludwigia leptocarpa (Onagraceae)

Résumé

Three new oleanane-type saponins, leptocarposide B-D (1–3), were isolated from the whole plant of Ludwigia leptocarpa (Nutt.) Hara, together with ten known compounds 4–13. The structures of these compounds were determined by interpretation of their spectral data, mainly HR-TOFESIMS, 1D-NMR (1H, 13C) and 2D-NMR (1H–1H COSY, HSQC, HMBC, and NOESY), and by comparison with the literature data. The structures of the new compounds were established as 28-O-β-d-xylopyranosyl-(1 → 4)-α-l-rhamnopyranosyl-(1 → 2)-[α-l-arabinopyranosyl-(1 → 3)]-4-O-(3′-hydroxybutanoyloxy-3-hydroxybutanoyloxy)-β-d-fucopyranosyl zanhic acid (1); 3-O-β-d-glucopyranosyl-28-O-β-d-xylopyranosyl-(1 → 4)-α-l-rhamnopyranosyl-(1 → 2)-4-O-(3′-hydroxybutanoyloxy-3-hydroxybutanoyloxy)-β-d-fucopyranosyl medicagenic acid (2); 3-O-β-d-glucopyranosyl-(1 → 4)-β-d-glucopyranosyl-28-O-β-d-xylopyranosyl-(1 → 4)-α-l-rhamnopyranosyl-(1 → 2)-[α-l- arabinopyranosyl-(1 → 3)]-4-O-(3′-hydroxybutanoyloxy-3-hydroxybutanoyloxy)-β-d-fucopyranosyl zanhic acid (3).
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hal-03407777 , version 1 (28-10-2021)

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Florence Déclaire Mabou, David Ngnokam, Dominique Harakat, Laurence Voutquenne-Nazabadioko. New oleanane-type saponins: Leptocarposide B-D, from Ludwigia leptocarpa (Onagraceae). Phytochemistry Letters, 2015, 14, pp.159-164. ⟨10.1016/j.phytol.2015.10.008⟩. ⟨hal-03407777⟩
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